林雲山（Yun-Shan Lin）

Email: ysl@mail.tku.edu.tw

研究專長及興趣

    本實驗室研究的對象是薁化合物之反應，包括親電子、親核、以及氧化反應，尤其是探討簡單方法及產率高的重輕昆之光化學反應合成Bisazulene，含有薁的環多醚。含有薁環的光電材料。

This Lab. focus on the chemical reactions of azulene derivatives including electrophilic, nucleophilic and oxidation reactions. Especially, the study on the convenient synthesis of azulenequinone derivatives in a high yield and photochemical reaction of various diazoquinones for the synthesis of cyclic azulene poly ethers. Synthesis of conducting materials including azulene moiety.

代表性著作

A.期刊論文

1. Tian-Chyuan Huang, Yun-Shan Lin, Shih-Jue Lin, and Shu-Fan Chu, Diazotization of Methyl 3-Amino-7-isopropyl-2-methoxyazulene-1-carboxylate and its 5-Isopropyl Isomer-A Convenient Synthesis of 1,2-Azulenequinone Derivatives, J. Chin. Chem, Soc., 43, 41-44,(1996).

2. Tian-Chyuan Huang, Yun-Shan Lin, and Tetsuo Nozoe, Synthesis and Polybromination of Azulene[6,5-d]thiazole and It‘s 2-Methyl Derivatives, Heterocycles, 43, 1049(1996).

3. Tian-Chyuan and Yun-Shan Lin,The Versatile Synthesis of Azulenothiazole Derivatives, J. Chin. Chem. Soc., 43, 365(1996).

4. Tian-Chyuan Huang, Shang-Ya Chiang, and Yun-Shan Lin, The Crystal Structure of Methyl 2-Diazo-3-cyano-4-oxo-2.4-dihydroazulene-1-carboxylate, Formosan Science, 49,38-46(1996).

5. Novel Bromination of Diethyl 2-Aminoazulene-1,3-dicarboxylate Tadayoshi Morita, Pai-Feng Tsai, Shin-Min Chen, Fa-Ching Chen, and Yun Shan Lin Sci. Rept Tohoku Univ. 78, 9-16(1996).

6. S-J Lin, S-Y Jiang, T-C Huang, P Kao,F. Tsai,H. Takeshita, Y-S Lin, and (the late)T. Nozoe. Photolysis of Diethyl 2-Diazo-6-oxo-2,6-dihydroazulene-1,3-dicarboxylate and Methyl 3-Cyano-2-diazo-6-oxo-2,6-dihydroazulene-1-carboxylate in Tetrahydrofuran. Hetrocycles, 45, NO.10 1879-1882(1997).

7. S-J Lin, S-Y Jiang, T-C Huang, C.-S. Dai, F. Tsai,H. Takeshita, Y-S Lin, and (the late)T. Nozoe. A New Convenient Synthesis of 1-2’-Biazulenes by Photolysis of 2-Diazo-1,3-dicyano-2,6-dihydroazulene-6-one with Azulene Derivatives, Bull.Chem. Soc. Jpn. 70, NO.12, 3071(1997).

8. Y-S.Lin, S-Y,Jiang,T-C Huang, S-J Lin and Y-L Chow, A New Method for Synthesis of Polyether Bridged Azulenes; Reactions of Conjugated Keto-carbenes Generated from the Corresponding Azulenoquinone Diazides, J.Org, Chem, 1998, 63,3364-3370.

9. Y-S Lin, T-C Huang, S-Y Jiang, C-Y Huang, Teruo Kurihara, Hitoshi Takeshita and Tetsuo Nozoe, The Lead(IV) Oxide Mediated Oxidation of Azulen-2-ol to Form 1.1-Coupled Dimers and Hexacyclic Cage-Dimers. Bull. Chem. Soc. Jpn, 2000, 73,2793-2803

10. Bo-Cheng Wang, Yun-shan Lin, Jian-Chuang Chang and Pei-Y Wang, Theoretical Studies of Azulene and It's Derivatives, Can. J. Chem. 2000, 78, 224-232.

11. Y-S Lin, P-T Kuo, S-T Lin, S-Y Jiang, and C-Y Huang Synthesis and Photolysis of Dibenzyl 2-Diazo-6-oxo-2,6-dihydroazulenequinone-1,3-dicarbonxylate-first Example of Intermolecular C-H Insertion and Intermolecular Electrophilic Substitution on Benzene in the Diazoazulenequinon. Polycycle Aromatic hydrocabms, special issues 2000(Accepted).

12. Ling, Hao-Jan; Chen, Kan-Nan; Lai,Jian-Zei; and Lin, Yun-shan, Uretedione derivative, curable resin composition comprising the same, and process for producing the same. US Patent,6,077,960, Jun.20,2000.

13. Tsoring-Wen Chen, Jen-Yeh, Kan-Nan Chen, and Yun-Shan Lin, Curable system of self-Emulsified Aqueous Epoxy Resin and Its Polymeric Hybrid,US Patent,6,291 55 431, Sep,2001.

14. Bo-Chen Wang, Houng-Wei Wang, I-Chun Lin, Yun-Shan Lin, Yu-Ma Chou and Houn-Lin Chiu, A Semienpirical Study of Carbon Nanotubes with Finite Tubular Length and Various Tubular Diameters. J. Chin. Chem. Soc., 2003, 50,939-945

15. 林雲山、何東英、陳發清教授研究簡介-天然物化學之研究。化學,中國化學會,第六十一卷,第三期,375-384頁(2003)

16. Bing-Bing Lin, Tadayoshi Morita, Yun-Shan Lin and Hui-Ling Chen. Facile synthesis of 1-ethoxy-4-cyano-5-ethoxycarbonyl-3H-azulenol[1,2-c]pyran-3-one, a selective 1,5-lipoxygenase inhibitor, Bioorg. Med. Chem. Lett. ,14(2004),63-65

B.會議論文

1. Y-S Lin, S-J Lin, T-C Huang, T. Morita and T. Nozoe, The Formation of Diethenodicyclopenta [ef:kl] heptalene(Diethenoazupyrene)Derivatives, Proceedings of 1996 International. Symposium on Organic Reactions-Sendai,p122(1996),Apr.6-9 1996, Sendai. Japan.

2. T.Nozoe, T-C Huang, M-H Shyr, H. Takeshita, S-Y Chiang and Y-S Lin, Photochemical Reactions of Diazoazulenequinone in Aprotic Solvents, ibid., p148(1996), April. 6-9, 1996, Sendai. Japan.

3. T-C Huang, S-Y Chiang and Y-S Lin, Synthesis of Novel Macrocyclic Polyethers Containing Azulene Unit. 中國化學會暨高雄分會年會，八十五年度手冊，207頁（Dec,7,1996）

4. 原田宣之，江原 均，守田忠義，林雲山，林世智，野副鐵男，二量體化合物 光學分割 圓二色性 舉動，化學系七學協會東北大會，八戶市，青森縣，日本國，1996年10月2~3日.

5.林世智，江選雅，黃添銓，戴政賢，蔡百豐，林雲山，H. Takeshita, T. Nozoe A New Convenient Synthesis of 1,2’-Biazulene by Photolysis of 2-Diazo-1, 3-dicyanoazulene-6-(2H)-one with Azulene Derivatives. 中國化學會86年年會手冊，274頁(1997)新竹工業技術研究院.

6. Y-S Lin and S-Y Jiang, An Improved Synthesis of 2-Arylazulene Derivatives, The 9^th International Symposium of Novel Aromatic Compounds (ISNA-9), 2nd-7th August, 1998, Theatre II, Hong Kong Convention Exhibition center, Wanchai, Hong Kong.

7. Y-S Lin, P-T Kuo, S-T Lin, S-Y Jiang, and C-Y Huang Synthesis and Photolysis of Dibenzyl 2-Diazo-6-oxo-2,6-dihydroazulenequinone-1,3-dicarbonxylate-first Example of Intermolecular C-H Insertion and Intermolecular Electrophilic Substitution on Benzene in the Diazoazulenequinon. The 7^th. International Symposium on Polycyclic Aromatic compounds. Oct. 25-29, 1999, Convention center, Bordeaux, France, Abstr. p99.

8. Y-S Lin, Hsing-Lin Jiang, Shuan-Ya Jiang, and Chien-Yi Huang, Synthesis of 1-Diazo-8-xix-1,8-dihydroazulenequinone and It's Potolysis in various solvents. 8th Asian Chemical congress, Nov. 21-24,1999. International Convention Center, Taipei, Taiwan, Abstr. p549.