淡江大學 | 中文 | English

 

魏和祥(Ho-Hsiang Wei)

無機化學、 分子磁性、生物無機化學

淡江大學化學系教授1975-迄今)
日本國立東京大學理學博士1972
淡江大學化學系學士1963

Tamkang University, Professor
University of Tokyo, Dr. S.
Tamkang University, B. S.


魏和祥

E-mail address: tkwei@mail.tku.edu.tw

研究專長及興趣

錯鹽化學  生物無機  分子磁性  磁性化學  梅思堡光譜

本實驗是主要研究在於分子設計模擬生物活性之無機錯化合物與構成鐵磁性之分子磁體(包括無機、有機及有機金屬化合物),利用SQUID變溫磁性測定,ESRRamanMössbauer光譜學探討分子集合體之自旋狀態及磁性。

The area of research interest are molecular designm synthesis, ESR, Raman, Mössbauer spectroscopic and SQUID magnetic investigations of (1)the biological model compounds of homo- or heter-binulcear and polynuclear transition-metal complexes of copper, iron, manganese ions, and (2)the ferro- antiferro- magnetic compounds of organic radicals and transition metal ions.

近年代表性著作

  1. H. L. Shyu, H. H. Wei, G. H. Lee and Yu Wang ," Synthesis and Characterization   of a New Binuclear Copper(II) Complex with Oxygen-bridged and B-N Bonded   Ligand"  Inorg. Chem. 1996, 35, 5396.

  2. D. M. Hong, H. H. Wei, L. L. Gan, G. H. Lee and Yu Wang "Synthesis, Structure and Magnetic Properties of Mononuclear [Mn(2,2'-bipyrimidine)2(H2O)2][ClO4]2 and Polynuclear[Mn(2,2'bipyrimidine)(NO3)2] Complexes "Polyhedron. 1996, 15, 2335-2340.

  3. H. H. Wei, H. Y Wong, G. H. Lee and Yu Wang, " Ferro- and Antiferromagnetic  Properties of Metal Complexes with Pyridine-substituted Nitronyl Nitroxide Radical."   J. Chin. Chem. Soc., 1996 , 43, 253-259.

  4. C. T. Lin and H. H. Wei et al  "Biogels of Cytochrome c : Cytochrome c Peroxidase Complex Studies by Electron Paramagnetic Resonance Spectroscopy"  J. Sol-Gel Sci. and Technology.  1996, 7,19-26.

  5. S. F. Huang, H. H. Wei and Yu Wang."A New Cyano-bridged One-dimensional Polymeric Mixed-valence Cu(II)/Cu(I) complex Formation from a Binuclear Cu(II) Complex with Sodium Cyanide"  Polyhedron. 1997, 16, 1747-1753.

  6. H. L. Shyu, H. H. Wei and Yu Wang , "Preparation, Characterization and Crystal Structure of [Ni(bpy)3][Fe(CN)5(NO)]3H2O and One-dimensional Cyano-    Bridged [Ni(en)2Fe(CN)5(NO)]H2O"  Inorg. Chim. Acta. 1997, 258, 81-86

  7. C. F. Huang , H. H. Wei, "Strong Antiferromagnetic Exchang in Cobalt(II)   Complexes with Ortho-substituted  Nitonyl Nitroxide Radical Ligand." J. Chin. Chem. Soc. 1997, 44, 439-443.

  8. H. F. Chung, H. H. Wei, G. H. Lee and Yu. Wang, " Magneto-structural Correlations and Chetacholase-like Activity of Binuclear Copper(II) Complexes with 1-diethylaminopropan-2-ol, N3-, NCO- and NO2- ligands." J. Chem. Soc., Dalton Trans.,1997, 2825-2829. 

  9. H. F. Chung , H. H. Wei, G. H. Lee , and  Yu Wang "Reinvestigation of The   crystal Structure and Cryomagnetic Behaviour of Copper(II) Propionates".   Polyhedron,. 1998, 17, 449-455.

  10. C. J. Lee, C. H. Hung, H. H. Wei, Y. H. Liu, G. H. Lee and Yu Wang,  Crystal Structures and Magnetic Properties of Mercurry(II) Bromide Complexes with Pyridyl-Substituted Nitronyl Nitroxide"  J. Chem. Soc., Dalton Transcations. 1998, 171-176.

  11. C. F. Huang, H. H. Wei, G. H. Lee and Yu Wang, "Structure and Magnetic   Properties of Novel Chloro-Bridged Polymeric Cadmium(II)Complex with   Pyridyl-Substituted Nitronyl Nitroxide" , Inorg. Chim. Acta. 1998, 279, 233-237.

  12. C. J. Lee, H. H. Wei, G. H. Lee and Yu Wang, “ Crystal Structure and Magnetic   Properties of Pyridyl-substituted Nitronyl NitroxidesJ. Chin. Chem. Soc.,   1998, 45, 349-353.

  13. D. M. Hong, H. H. Wei, K. H. Chang, G.  H. Lee and Yu  Wang "Magneto-  structural correlations and Catalase-like Activity for H2O2 Disproportionation   of Bis(acetylscetonato)manganese(II)Complexes with Diazine Compounds"  J. Chin. Chem. Soc., 1998, 45, 701-706.

  14. D. M. Hong, H. H. Wei, K. H. Chang, G. H. Lee and Yu Wang " Structure, and Magnetic Properties of Bis(1,1,1,5,5,5-hexafluoropentane-2,4 dionate)manganese(II) Complexes with Diazine Ligands. "Polyhedron, 1998, 27, k-3565-3573.

  15. H. L Shyu, H. H. Wei and Yu Wang " Synthesis, Structure and  Magnetic Properties  of  [Cu(bpy)2][Fe(CN)5NO]XH2O and [Cu(en)2][Fe(CN)5NO]XH2O"   J. Coord. Chem. 1998, 47, 319-330 .

  16. H. L. Shuy, H.-H. Wei and Yu Wang, “ Structure and Cyromagnetic Properties of Dinuclear [MnIII(salen)(H2O)]2(ClO4)2 and Polynuclear [MnIII(salen)(NO3)]nInorg. Chim. Acta. 290, 8-13, 1999. 

  17. H. H. Wei, A. R. Li and L. L. Gan,” Structure, Magnetic Properties and Catalase-  like activity of (m-oxo)bis[meso-tetrakis(p-tolyl-porphyrinato)iron(III)] and (m-  oxo)bis[N,N’-ethylenebis(2-acetylphenoliminato)iron(III)], Inorg. Chim. Acta. 290, 51-56, 1999. 

  18. H. F. Chung, H. H. Wei , G. H. Lee, Y. H. Liu and Yu Wang, “ Magnetostructural Correlation of  Dicopper(II) Teracarboxylate Complexes With Pyrdyl-nitronyl NitroxiseInorg, Chim. Acta, 293, 30-36, 1999.

  19. H. F. Chung and H. H. Wei, “ Structure and Magnetic Property of A Novel Polymeric Dinuclear Copper(II) Tetramethylacetate complex with 2-(3-Pyridyl)4,4,5,5-tetramethylimidazoline-1-oxyl 3-oxide”. Inorg. ChemCommun., 2, 269-271, 1999

  20. K. H. Chang, H. H. Wei and D. M. Hong ,” Structure, Cryomagnetic Properties and Catalase-like Activity of Asymmetric Dimanganese(III) Carboxylato Complexes with Salicylaldimine Ligands”. J. Chin. Chem. Soc., 1999, 46, 911-916. 

  21. H. L. Shyu, H. H. Wei, G. H. Lee and Yu. Wang, "Structure, Magnetic properties and Epoxidation Activity of Iron(III) Salicylaedimine complexes" J. Chem. Soc., Dalton Trans., 2000,915-918.

  22. C. J. Lee, H. H. Wei, “ A Novel chloro-bridged Tetranuclear Cadmium(II) cluster with pyridyl-substituted Nitronyl Ntroxide Complex: structure and magnetic properties. ”  Inorg. ChemCommun. 2000,3.690-693.

  23. C. J. Lee and H. H. Wei, "Crystal structure and Magnetic properties of Zine(II) Hexafluoroacetylacetonate complex with Pyridyl-substituted Nitronyl Nitroxide Ligands" Inorg. Chim. Acta. 2000,310,89-95.

  24. W. H. Chen, H. H. Wei, G. H. Lee and Yu. Wang, "Dimeric Irom(III) Complexes with Salicylaldimine Ligands, Structure, Magnetic properties and Catalase-like Activities" Polyhedron. 2001,20,515-521.

  25. C.J.Lee, H.H.Wei, G.H.Lee and Yu Wang, "Synthesis, Crystal structure and Magnetic properties of Znic(II) Chloride Complexes with Pyridyl-Substituted Nitronyl Nitroxides" J.Chin. Chem. Soc. 2001,48,717-722.

  26. C.H.Kao, H.H.Wei, Y.H.Liu, G.H.Lee, Yu Wang. C. J. Lee," Structural Correlation of Catecholase-like Activities of Oxy-bridged Ainuclear Copper(II) Complexes " J. Inorg. Biochem., 2001,84,171-181.

  27. H.H.Lin and H.H.Wei, "Structure and Magnetic Properties of Copper(II) Corboxylate Complexes", Polyhedron,2001,20,3057.

  28. S. Mohanta, H. H. Lin, C. J. Lee and H. H. Wei " A Two-dimensional Cu(II)GD(III) compound self-assembled by H-Bonding and Intermolecular weak coordinate bonding between the dinuclear cores : structure and magnetic properties" Inorg. Chem. Commun. 2002, 5, 585-588.

  29. M.T. Wang, H.H. Wei, and Yu Wang " Structure, Magnetic Properties, MÖssbauer spectra and Catalse-like Activity of Spin Crossover Fe(III) Complexes with Salicylaldimine Ligands :" J. Chin. Chem. Soc. 2002 (in press).

  30. S. C. Cheng and H. H. Wei " Structure, magnetic properties and catecholase activity study of oxo-bridged dinuclear copper(II) complexes " Inorg. Chim. Acta. 2002 ( in press).

  31. T.W.Chang, H.L. Shyu, G.H. Lee and Yu Wang " Structure, Magnetic Properties and Catalytic Activity of Olefins-Epoxidatoin of Iron(III) and Mn(III) Salicylaldimine Complexes. J. Chinese. Chem. Soc. 2002, (in press).