淡江大學 | 中文 | English

 

謝忠宏(Chung-Hung Hsieh)

無機化學 生物無機化學


               美國德州農工大學 化學系

               國立清華大學 化學系

               國立彰化師範大學 化學系

Assistant Research Scientist (2011, Nov.-  2013, Jul. )
Texas A&M University, College Station, Texas, USA
Research Advisor: Professor Marcetta Y. Darensbourg
                                              
Postdoctoral Research Associate (2009, Nov.-2011, Jul.)
Texas A&M University, College Station, Texas, USA
Research Advisor: Professor Marcetta Y. Darensbourg
 
Post Doctor (2008, Feb.-2008, Jul.; 2009, Aug.-2009, Oct.)
National Tsing Hua University, Hsinchu, Taiwan
Research Advisor: Professor Wen-Feng Liaw
 

謝忠宏
 
 
聯絡方式
      e-mail : chsieh@mail.tku.edu.tw

     學校分機 : 02-26215656 # 2538

 

發表論文

 

 

 
 
實驗室成員
 
 
研究助理
 
張芮琳
合成氫化酶的研究
 
研究生
 
碩士二 杜宛庭
鑑定仿氫化酶用於產氫的研究
碩士二 黃柏瑋
 無機化合物的合成
碩士二 張文劼
鈷過度金屬與磷、卡賓相關配位合成與分析
碩士一 陳俊淵
文劼小跟班2號
sofosbuvir化合物的晶體分析 與有機無機化合物合成
碩士一 周庭宇
文劼小跟班3號
sofosbuvir化合物的晶體分析 與無機化合物合成 
  
專題生
 
大四 高士捷
文劼小跟班4號
合成氫化酶的研究
大四 周家男
 
文劼小跟班5號
鐵離子與卡賓的合成與分析研究 
大四 蔡棠聿
 
文劼小跟班6號
靈菌紅素的分析研究
大四 宋名康
 
文劼小跟班7號
鐵離子與卡賓的合成與分析研究 
大三 杜昊哲
文劼小跟班1號
與張文劼共同研究 
大三 陳心怡
與周家男共同研究
兼文劼小跟班8號
大三 高健傑
與黃柏瑋共同研究
兼文劼小跟班9號
大三 陳逸修
與周庭宇、陳俊淵共同研究
兼文劼小跟班10號
大三 林煜程
與高士捷、杜宛庭共同研究
兼文劼小跟班11號
大三 呂明洋
與張芮琳共同研究
兼文劼小跟班12號
大三 張瓈云
與陳俊淵共同研究
大三 陳湘婷
與張芮琳共同研究
 
 
 

發表論文
 
 
1.  A Reduced 2Fe2S Cluster Probe of Sulfur-Hydrogen vs. Sulfur-Gold Interactions,
Crouthers, D. J.; Ding, S.; Denny, J. A.; Bethel, R. D.; Hsieh, C.-H.; Hall, M. B.; Darensbourg, M. Y., 
Angew. Chemie, Int. Ed.,2015,54,Accepted manuscript.
2.  Regioselectivity in Ligand Substitution Reactions on Diiron Complexes Governed by Nucleophilic and Electrophilic Ligand Properties.
Bethel, R. D.; Crouthers, D. J.; Hsieh, C.-H.; Denny, J. A.; Hall, M. B.; Darensbourg, M. Y. 
Inorg. Chem.2015,54,3523-3535.
3.  Metallodithiolates as Ligands to Dinitrosyl Iron Complexes: Toward the Understanding of Structures, Equilibria, and Spin Coupling.
Pinder, T. A.; Montalvo, S. K.; Hsieh, C.-H.; Lunsford, A. M.; Bethel, R. D.; Pierce, B. S.; Darensbourg, M. Y., 
Inorg. Chem.,2014,53.90959105.
4.  Hammett correlations as test of mechanism of CO-induced disulfide elimination from dinitrosyl iron complexes.
Pulukkody, R.; Kyran, S. J.; Drummond, M. J.; Hsieh, C.-H.; Darensbourg, D. J.; Darensbourg, M. Y., 
Chem.Sci.,2014,5,37953802. 
5. Redox active iron nitrosyl units in proton reduction electrocatalysis.
Hsieh, C.-H.; Ding, S.; Erdem, Ö. F.; Crouthers, D. J.; Lubitz, W.; Popescu, C. V.; Reibenspies, J. H.; Hall, M. B.; Darensbourg, M. Y.,
Nature Communications,2014,5,Article number 3684.
6.   A Dinitrosyl Iron Complex as a Platform for Metal-Bound Imidazole to N-Heterocyclic Carbene Conversion
    Randara Pulukkody , Samuel J. Kyran , Ryan D. Bethel , Chung-Hung Hsieh , Michael B. Hall , Donald J. Darensbourg, Marcetta Y. Darensbourg, 
    Chem. Comm. 2013, 49, 9326-9328.
   
7.  Versatile N2S2 Nickel-dithiolates as Mono- and Bridging Bidentate, S-donor Ligands to Gold(I).
Pinder T. A.; Montalvo, S. K.; Lunsford, A. M.; Hsieh,C.-H.; Reibenspies,J. H.; Darensbourg, M. Y.*
Dalton Trans., 201343, 138-144. 
 
8.  Carbon Monoxide Induced Reductive Elimination of Disulfide in an N-Heterocyclic Carbene (NHC)/ Thiolate Dinitrosyl Iron Complex (DNIC)
Randara Pulukkody , Samuel J. Kyran , Ryan D. Bethel , Chung-Hung Hsieh , Michael B. Hall , Donald J. Darensbourg, Marcetta Y. Darensbourg,
J. Am. Chem. Soc.2013, 135, 8423-8430.
 
9.   Ambidentate Thiocyanate and Cyanate Ligands in Dinitrosyl Iron Complexes,
Chung-Hung Hsieh, Scott M. Brothers, Joseph H. Reibenspies, Michael B. Hall, Codrina V. Popescu, Marcetta Y. Darensbourg,
Inorg. Chem2013, 52, 2119-2124.
 
10.  Bridging-Hydride Influence on the Electronic Structure of an [FeFe]-Hydrogenase Active-Site Model Complex Revealed by XAES-DFT
N. Leidel, C-H Hsieh, P. Chernev, K. G. V. Sigfridsson, M. Y. Darensbourg, M. Haumann,
Dalton Trans.2013, 42, 7539-7554.
 
11.  Hyperfine interactions and electron distribution in Fe(II)Fe(I) and Fe (I)Fe (I) models for the active site of the [FeFe] hydrogenases: Mossbauer spectroscopy studies of low-spin Fe(I)
Sebastian A. Stoian , Chung-Hung Hsieh, Michael L. Singleton, Andrea F. Casuras, Marcetta Y. Darensbourg, Kelsey McNeely, Kurt Sweely, Codrina V. Popescu,
J. Bio. Inorg. Chem.2013, 18, 609-622.
 
12.   Structural and Spectroscopic Features of Mixed Valent FeIIFeI Complexes and Factors Related to the Rotated Configuration of Diiron Hydrogenase.
Hsieh, C.-H.; Erdem, Ö. F.; Harman, S. D.; Singleton, M. L.; Reijerse, E.; Lubitz, W.; Popescu, C. V.; Reibenspies, J. H.; Brothers, S. M.; Hall, M. B.; Darensbourg, M. Y., 
J. Am. Chem. Soc2012,134, 13089–13102.
 
13.  Dinitrosyl Iron Adducts of (N2S2)M(NO) Complexes (M = Fe, Co) as Metallodithiolate Ligands
Chung-Hung Hsieh, Rachel B. Chupik, Tiffany A. Pinder, Marcetta Y. Darensbourg,
Polyhydron2013, 58, 151-155.
 
14.  Towards Understanding the Electronic Response of the Fe(NO)2 Unit to “Spectator” Ligands in Dinitrosyl Iron Complexes
Brothers, S. M.; Hess, J. L.; Hsieh, C.-H.; Darensbourg, M. Y.*; Hall, M. B.*
Structure and Bonding2012, submitted.
 
15.  Self-Assembly of Dinitrosyl Iron Units into Imidazolate-Edge-Bridged Molecular Squares: Characterization Including Mossbauer Spectroscopy,
J. L Hess, C.-H. Hsieh, S. M. Brothers, M. B. Hall, M. Y. Darensbourg,
J. Am. Chem. Soc. 2011, 133, 20426–20434
 
16.  N-Heterocyclic carbene ligands as mimics of histidines for the stabilization of di- and tri-nitrosyl iron complexes,
Jennifer L. Hess, Chung-Hung Hsieh, Joseph H. Reibenspies, M. Y. Darensbourg,
Inorg. Chem. 2011, 50, 8541-8552. 
 
17.   cis-Dithiolatonickel as Metalloligand to Dinitrosyl Iron Units: the Di-Metallic Structure of Ni(μ-SR)[Fe(NO)2] and an Unexpected, Abbreviated Metalloadamantyl Cluster, Ni2(μ-SR)4[Fe(NO)2]3,
  Chung-Hung Hsieh, Rachel B. Chupik, Scott M. Brothers, Michael B. Hall, Marcetta Y. Darensbourg,
Dalton Trans. 2011, 40, 6047-6053. 
 
18.   A {Fe(NO)3}10 Trinitrosyliron Complex Stabilized by an N-Heterocyclic Carbene and the Cationic and Neutral {Fe(NO)2}9/10 Products of Its NO Release
Chung-Hung Hsieh, Marcetta Y. Darensbourg,
J. Am. Chem. Soc.,2010,132, 1411814125.
 
19.  Nitric Oxide Physiological Responses and Delivery Mechanisms Probed by Water-soluble Roussin’s Red Ester and {Fe(NO)2}10 DNIC.
Chen, Y.-J.; Ku, W.-C.; Feng, L.-T.; Tsai, M.-L.; Hsieh, C.-H.Hsu, W.-H.; Liaw, W.-F.*; Hung, C.-H.*; Chen, Y.-J.*
J. Am. Chem. Soc2008, 130, 10929-10938.
 
20.   Dinitrosyl Iron Complexes (DNICs) Containing S/N/O Ligation: Transformation of Roussin’s Red Ester into the Neutral {Fe(NO)} DNICs
Tsai, M.-L.; Hsieh, C.-H.; Liaw, W.-F.*
Inorg. Chem.200746, 5110-5117
 
21.   New members of a Class of Iron-Thiolate-Nitrosyl Compounds: Trinuclear Iron-Thiolate-Nitrosyl Complexes Containing FeS Core
Hsu, I.-J.; Hsieh C.-H.; Ke S.-C.*; Chiang K.-A.; Lee J.-M.; Chen J.-M.; Jang L.-Y.; Lee G.-H.; Wang Y.*; Liaw, W.-F.*
J. Am. Chem. Soc. 2007129, 1151-1159
 
22.  Photochemistry of the Dinitrosyl Iron Complex [S5Fe(NO)2]- Leading to Reversible Formation of [S5Fe(μ-S)2FeS5]2-: Spectroscopic Characterization of Species Relevant to the Nitric Oxide Modification and Repair of [2Fe-2S] Ferredoxin
Tsai, M.-L.; Chen, C.-C.; Hsu, I.-J.; Ke, S.-C.; Hsieh, C.-H.; Chiang, K.-A.; Lee, G.-H.; Wang, Y.; Chen, J.-M.; Lee, J.-F.; Liaw, W.-F. * 
Inorg. Chem.200443, 5159-5167
 
23.   Oxygen Binding to Sulfur in Nitrosylated Iron-Thiolate Complexes: Relevance to the Fe-Containing Nitrile Hydratases
Lee,C.-M.; Hsieh, C.-H.; Dutta, A.; Lee, G.-H.; Liaw, W.-F.*
J. Am. Chem. Soc. 2003125, 11492-11493
 
24.   Nickel Complex of o-amidochalcogenophenolate (2-) /o-iminochalcogenobenzosemiquinonate (1-) π-radical: Synthesis, Structures, Electron Spin Resonance and X-ray Absorption Spectroscopic Evidence
Hsieh, C.-H.; Hsu, I-J.; Lee, C.-M.; Ke S.-C.; Wang T.-Y.; Lee G.-Hs.; Wang, Y.; Chen, J.-M.; Lee, J.-F.; Liaw, W.-F.*
Inorg. Chem. 200342, 3925-3933.
 
25.   Bioinorganic and Coordinated Chemistry
Chen; C.-H.; Lee, C.-M.; Hsieh, C.-H.; Liaw, W.-F.*
Chemistry (The Chinese Chem. Soc., Taipei) 200361, 79-86.
 
26.   S-S Bond-activation of diorganyl disulfide by anionic [Mn(CO)5]: crystal structures of [MnII(SC5H4NO)3] and [(CO)3Mn(μ-SR)3Co(μ-SR)3Mn(CO)3] (R=C6H4NHCOPh)
Liaw, W.-F.*; Hsieh, C.-H.; Lee G.-H.
Inorg. Chim. Acta. 2002332, 153-159
 
27.   Five-Coordinate Sixteen-Elecron Manganese(I) Complex [Mn(CO)3(S, S-C6H4)]- Stabilized by S, S π-Donation of Chelating [S, S-C6H4)]2- Ligand
Lee,C.-M.; Lin, G.-Y.; Hsieh, C.-H.; Hu, C.-H.; Lee G.-H.; Peng S.-M.; Liaw, W.-F.*
J. Chem. Soc., Dalton Trans. 1999, 2393-2398
 
 

 

 

演講 (2012-  )

The 245th American Chemical Society National Meeting & Exposition, 2013

Division of Inorganic Chemistry:

Ambidentate thiocyanate ligand in dinitrosyl iron complexes

 

The 244th American Chemical Society National Meeting & Exposition, 2012

Division of Inorganic Chemistry:

Base-Promoted Tautomerization of Imidazoles to N-Heterocyclic Carbenes (NHCs): via a Dinitrosyl Iron scaffold